Please use this identifier to cite or link to this item: http://www.repositorio.cdtn.br:8080/jspui/handle/123456789/1282
Title: A new designed π conjugated molecule for stable single walled carbon nanotube dispersion in aqueous medium
Title of periodic: Journal of Colloid and Interface Science
Authors: Nogueira, S.L.
Sahoo, S.K.
Jarrosson, T.
Serein-Spirau, F.
Lère-Porte, J. P.
Marletta, A.
Santos, Adelina Pinheiro
Fantini, C.
Furtado, Clascidia Aparecida
Silva, R.A.
Affiliation: Universidade Federal de Uberlândia, UFU, Uberlândia, MG, Brasil
Universidade Federal de Minas Gerais, UFMG, Belo Horizonte, MG, Brasil
Institut Charles Gerhardt Equipe AM2NArchitectures Moléculaires et Matériaux Nanostruturés ENSCM, Montpellier, France
Institut Charles Gerhardt Equipe AM2NArchitectures Moléculaires et Matériaux Nanostruturés ENSCM, Montpellier, France
Institut Charles Gerhardt Equipe AM2NArchitectures Moléculaires et Matériaux Nanostruturés ENSCM, Montpellier, France
Universidade Federal de Rondônia, Porto Velho, Brasil
Universidade Federal de Uberlândia, UFU, Uberlândia, MG, Brasil
Centro de Desenvolvimento da Tecnologia Nuclear, CDTN, Belo Horizonte, MG
Universidade Federal de Minas Gerais, UFMG, Belo Horizonte, MG, Brasil
Centro de Desenvolvimento da Tecnologia Nuclear, CDTN, Belo Horizonte, MG
Universidade Federal de Uberlândia, UFU, Uberlândia, MG, Brasil
Issue Date: 2016
Keywords: Carbon;Nanotubes;Nanostructures
Abstract: A molecule with a π conjugated backbone built from aromatic thiophene and dialkoxyphenylene units and substituted imidazolium groups (TPO) is designed to obtain ultra-stable single walled carbon nanotube (SWCNT) dispersion in aqueous medium. The proposed mechanism of non-covalent interaction is accompanied by individualization of SWCNT and comprises of dominant nondisruptive π-π and cation-π interaction between them and the TPO conjugated oligomer. The individualization of SWCNT and dispersibility and stability of the ultra-stable suspensions were estimated using high resolution transmission electron microscopy, UV-Visible-NIR absorption spectroscopy, Raman spectroscopy, photoluminescence and zeta potential measurement. Nuclear magnetic resonance data provides direct evidence toward possible cation-π interaction.
Access: R
Appears in Collections:Artigo de periódico

Files in This Item:
File Description SizeFormat 
A new designed conjugated molecule for stable single walled carbon.pdf1.43 MBAdobe PDFView/Open    Request a copy


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.