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Título: Sais de tetrafenilfosfônio e tris(1,10-fenantrolina)ferro(II) de complexos aniônicos de dibutilestanho(IV) com ditiocarbimatos: síntese, caracterização e atIVidade antifúngica
Título do periódico: Química Nova
Autor(es): Bottega, Fernanda C.
Oliveira, Marcelo Ribeiro Leite
Rubinger, Mayura Marques Magalhães
Bellato, Carlos Roberto
Ardisson, José Domingos
Zambolim, Laércio
Afiliação: Universidade Federal de Viçosa, UFV, Viçosa, MG, Brasil
Universidade Federal de Viçosa, UFV, Viçosa, MG, Brasil
Universidade Federal de Viçosa, UFV, Viçosa, MG, Brasil
Universidade Federal de Viçosa, UFV, Viçosa, MG, Brasil
Centro de Desenvolvimento da Tecnologia Nuclear, CDTN, Belo Horizonte, MG, Brasil
Universidade Federal de Viçosa, UFV, Viçosa, MG, Brasil
Data do documento: 2016
Palavras-chave: Fungicides;Organometallic compounds
Resumo: TETRAPHENYLPHOSPHONIUM AND TRIS (1.10-PHENANTHROLINE) IRON(II) SALTS OF ANIONIC COMPLEXES OF DIBUTYLTIN(IV) WITH DITHIOCARBIMATES: SYNTHESIS, CHARACTERIZATION AND ANTIFUNGAL ACTIVITY. Six new salts of organometallic complexes of tin(IV) with the general formulae: (Ph4P)2[Sn(Bu)2(RSO2N=CS2)2] and [Fe(phen)3] [Sn(Bu)2(RSO2N=CS2)2] [Ph4P = tetraphenylphosphonium, R = CH3 (1), C2H5 (2) and C4H9 (3); Fe(phen)3 = tris(1,10-phenanthroline) iron(II), R = CH3 (4), C2H5 (5) and C4H9 (6)] were synthetized from potassium dithiocarbimates (RSO2N=CS2K2.H2O) in reaction with dichlorobis-n-butyltin(IV) and tetraphenylphosphonium chloride (1-3) in N,N-dimethylformamide or tris(1,10-phenanthroline) iron(II) (4-6) in methanol. The new compounds were characterized by elemental analysis of Fe and Sn, and by vibrational, Mössbauer and nuclear magnetic resonance of 1H, 13C and 119Sn spectroscopies. High-resolution mass spectra in the negative and positive modes were also obtained. The elemental analyses and the exact masses obtained for the cations and the complex anions were consistent with the proposed formulae. The Mössbauer spectroscopic data were consistent with the presence of tin(IV) with coordination numbers between 4 and 5 (compounds 1-6), and of hexacoordinated iron(II) (compounds 4-6). The 1H and 13C NMR spectra presented all the expected signals for the cations and anions, and the signals observed in the 119Sn NMR spectra indicated an equilibrium between tetra- and pentacoordination around the tin atoms in solution. The in vitro activity of the new compounds was evaluated against Botrytis cinerea and Colletotrichum acutatum.
Acesso: L
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